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Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2007 Jul 07 (25), pp. 2658-68. Date of Electronic Publication: 2007 Apr 24. - Publication Year :
- 2007
-
Abstract
- The use of di-2-pyridyl ketone oxime (Hpko)/X- "blends" (X- = OH-, Cl-, ClO4-) in copper chemistry has yielded neutral binuclear and cationic trinuclear, pentanuclear or hexanuclear complexes. Various synthetic procedures have led to the synthesis of compounds [Cu5(pko)7].[ClO4]3.2CH3OH.2H2O (1), [Cu3(pko)3(OH)(Cl)]2[Ph4B]2.4DMF.2H2O (2), [Cu2(pko)4] (3), {[Cu6(pko)6ClO4(CH3CN)6][Cu6(pko)6(ClO4)3(CH3CN)4]}.8ClO4.14CH3CN.H2O (4). The structures of the complexes have been determined by single-crystal X-ray crystallography.
Details
- Language :
- English
- ISSN :
- 1477-9226
- Issue :
- 25
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 17576491
- Full Text :
- https://doi.org/10.1039/b700902j