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trans-[1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido(triphenylphosphine-kappaP)palladium(II).

Authors :
Sevinçek R
Türkmen H
Aygün M
Cetinkaya B
García-Granda S
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2007 Jun; Vol. 63 (Pt 6), pp. m277-9. Date of Electronic Publication: 2007 May 31.
Publication Year :
2007

Abstract

The title complex, [PdCl(2)(C(21)H(26)N(2))(C(18)H(15)P)], shows slightly distorted square-planar coordination around the Pd(II) metal centre. The Pd-C bond distance between the N-heterocyclic ligand and the metal atom is 2.028 (5) A. The dihedral angle between the two trimethylphenyl ring planes is 36.9 (2) degrees.

Details

Language :
English
ISSN :
0108-2701
Volume :
63
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
17551189
Full Text :
https://doi.org/10.1107/S0108270107021622