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New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes.

Authors :
Page PC
Farah MM
Buckley BR
Blacker AJ
Source :
The Journal of organic chemistry [J Org Chem] 2007 Jun 08; Vol. 72 (12), pp. 4424-30. Date of Electronic Publication: 2007 May 17.
Publication Year :
2007

Abstract

A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.

Details

Language :
English
ISSN :
0022-3263
Volume :
72
Issue :
12
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
17506579
Full Text :
https://doi.org/10.1021/jo070255w