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Stereoselective dimerization of racemic C3-symmetric Ti(IV) amine triphenolate complexes.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2007 Apr 28 (16), pp. 1573-6. Date of Electronic Publication: 2007 Mar 15. - Publication Year :
- 2007
-
Abstract
- A novel, mononuclear Ti(IV) amine triphenolate complex obtained by reaction of Ti(OiPr)(4) with tris(2-hydroxy-3-phenylbenzyl)amine bearing phenyl ortho-substituents affords quantitatively and spontaneously the corresponding heterochiral micro-oxo dinuclear compound whereas an analogous chiral, enantiopure complex maintains its mononuclear structure even in the presence of an excess of water.
Details
- Language :
- English
- ISSN :
- 1477-9226
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 17426858
- Full Text :
- https://doi.org/10.1039/b702958f