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An iron-catalysed hydrosilylation of ketones.

Authors :
Nishiyama H
Furuta A
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Feb 21 (7), pp. 760-2. Date of Electronic Publication: 2006 Dec 20.
Publication Year :
2007

Abstract

The combination of Fe(OAc)2 and multi-nitrogen-based ligands such as N,N,N',N'-tetramethyethylenediamine, bis-tert-butyl-bipyridine, or bis(oxazolinyl)pyridine can efficiently catalyse hydrosilylation of ketones to give the corresponding alcohols in high yields including asymmetric catalysis.

Details

Language :
English
ISSN :
1359-7345
Issue :
7
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
17392975
Full Text :
https://doi.org/10.1039/b617388h