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Photophysical studies and excited-state structure of a blue phosphorescent gold-thallium complex.
- Source :
-
Inorganic chemistry [Inorg Chem] 2007 Apr 16; Vol. 46 (8), pp. 2953-5. Date of Electronic Publication: 2007 Mar 21. - Publication Year :
- 2007
-
Abstract
- The dinuclear complex [[Tl(eta6-toluene)][Au(C6Cl5)2]] (1) displays very intense blue phosphorescence and a rigidochromic behavior in the solid state. The photophysical measurements in a glassy solution display an oligomerization process via metal-metal interactions. Density functional theory calculations show a distortion of the aurate-thallium T shape in the lowest triplet excited state, leading to a triplet metal-to-metal charge-transfer state.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 46
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17373786
- Full Text :
- https://doi.org/10.1021/ic062127g