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Isoquinolin-1-ylidenes as electronically tuneable ligands.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Mar 12 (11), pp. 1180-2. Date of Electronic Publication: 2007 Jan 10. - Publication Year :
- 2007
-
Abstract
- The novel isoquinolin-1-ylidene ligands, introduced into Rh(I) complexes by exploiting the carbene-like reactivity of adducts , exhibit ligand properties similar to those of classic NHCs, and their electronic properties can be tuned by the introduction of electron-withdrawing or donating groups in the benzene ring.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 17347732
- Full Text :
- https://doi.org/10.1039/b617037d