Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides.

Authors :: Wilden JD
Geldeard L
Lee CC
Judd DB
Caddick S
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Mar 14 (10), pp. 1074-6. Date of Electronic Publication: 2006 Dec 21.
Publication Year :: 2007
Abstract: 2,4,6-Trichlorophenol (TCP) sulfonate esters undergo effective aminolysis under conventional heating and microwave irradiation; the reactivity of these species is such that chemoselective transformations of PFP sulfonate esters can be achieved.

Subjects :: Chlorophenols metabolism
Esters chemistry
Molecular Structure
Sulfonic Acids metabolism
Chlorophenols chemistry
Esters chemical synthesis
Fluorobenzenes chemistry
Phenols chemistry
Sulfinic Acids chemistry
Sulfonamides chemical synthesis
Sulfonic Acids chemistry

Full Text Access

Tools