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X-ray photoreduction of a di(mu-oxo)Mn(III)Mn(IV) complex occurs at temperatures as low as 20 K.

Authors :
Dubois L
Jacquamet L
Pécaut J
Latour JM
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2006 Nov 21 (43), pp. 4521-3.
Publication Year :
2006

Abstract

Full reduction of the Mn(III)(mu-O)2Mn(IV) core to Mn(II)(mu-OH2)2Mn(II) is observed upon irradiation by an X-ray beam at ca. 20 K.

Details

Language :
English
ISSN :
1359-7345
Issue :
43
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
17283805
Full Text :
https://doi.org/10.1039/b609072a