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Templated assembly of water-soluble nano-capsules: inter-phase sequestration, storage, and separation of hydrocarbon gases.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2006 Dec 27; Vol. 128 (51), pp. 16498-9. - Publication Year :
- 2006
-
Abstract
- In aqueous solution, a deep-cavity cavitand was shown to self-assemble into dimeric nano-capsules via the sequestration of gaseous-phase hydrocarbons. The sequestration, assembly, and entrapment process was shown to be dependent on the hydrocarbon. Thus, by way of example, butane could be selectively sequestered from a propane-butane mixture.
- Subjects :
- Ethers, Cyclic chemical synthesis
Gases chemistry
Magnetic Resonance Spectroscopy methods
Models, Molecular
Molecular Conformation
Resorcinols chemical synthesis
Sensitivity and Specificity
Solubility
Time Factors
Water chemistry
Ethers, Cyclic chemistry
Hydrocarbons chemistry
Nanostructures chemistry
Resorcinols chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 128
- Issue :
- 51
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 17177388
- Full Text :
- https://doi.org/10.1021/ja0670916