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Optical rotation of achiral pentaerythritol.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2006 Nov 22; Vol. 128 (46), pp. 14746-7. - Publication Year :
- 2006
-
Abstract
- The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be +/-6 degrees /mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theoretical tensors were similarly oriented to within 5 degrees .
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 128
- Issue :
- 46
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 17105251
- Full Text :
- https://doi.org/10.1021/ja064631q