Separation of trace level hafnium from tungsten: a step toward solving an astronomical puzzle.

182Hf (T(1/2) = 9 x 10(6) y) is believed to be formed by pure r-process during a supernova explosion, and therefore, the search for minute traces of 182Hf in the earth's crust is of great interest. Only accelerator mass spectrometry (AMS) is well suited for detecting such low levels of 182Hf. But any attempt to measure 182Hf by AMS must ensure that the sample is free from its naturally occurring stable isobar 182W. A simple method for separation of tungsten and hafnium has been developed using radiometric simulation followed by checking the decontamination of tungsten from Hf in a synthetic sample by AMS. The separation studies were performed by a liquid-liquid extraction technique using tri-n-octylamine (TOA) as the organic reagent. It has been found that a very high separation factor (1.6 x 10(6)) can be achieved when 0.3 M TOA diluted in cyclohexane is used as the organic phase and 6 M HCl (in the presence of small amount of H2O2) is used as the aqueous phase.