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Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (eta-C5Me4R)2Ta2(mu-Cl)4(R = Me, Et) to a new mu-eta1,eta1-N2 complex and odd-electron organotrimetallic cluster.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2005 Nov 21 (43), pp. 5444-6. Date of Electronic Publication: 2005 Oct 04. - Publication Year :
- 2005
-
Abstract
- (C5Me5R)2Ta2Cl4 (d2-d2) disproportionates under dinitrogen to [(C5Me4R)TaCl2]2(mu-N2) and the D3h cluster cation (C5Me4R)3Ta3(mu-Cl)6+ with anionic (C5Me4R)TaCl4-.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 16261241
- Full Text :
- https://doi.org/10.1039/b508148c