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Experimental quantification of cavitation yield revisited: focus on high frequency ultrasound reactors.
- Source :
-
Ultrasonics sonochemistry [Ultrason Sonochem] 2006 Jan; Vol. 13 (1), pp. 1-5. Date of Electronic Publication: 2005 Feb 25. - Publication Year :
- 2006
-
Abstract
- Acoustic cavitation plays an important role in enhancing the reaction rate of chemical processes in sonochemical systems. However, quantification of cavitation intensity in sonochemical systems is generally limited to low frequency systems. In this study, an empirical determination of cavitation yield in high frequency ultrasound systems was performed by measuring the amount of iodine liberated from the oxidation of potassium iodide (KI) solution at 1.7 and 2.4 MHz. Experiments for determining cavitation were carried out at various solute (KI) concentrations under constant temperature, obtained by direct cooling of the solution and variable temperature conditions, in the absence of external cooling. Cavitation yield measurements, reported in this work, extend previously reported results and lend credence to the two step reaction pathway in high frequency systems. Additionally, the concentration of KI and temperature affect the cavitation yield of a system such that the iodine production is proportional to both conditions. It is proposed that direct cooling of sonicated KI solution may be advantageous for optimization of cavitation intensity in high frequency sonochemical reactors.
- Subjects :
- Chemical Industry instrumentation
Chemical Industry methods
Complex Mixtures chemistry
Complex Mixtures radiation effects
Dose-Response Relationship, Radiation
Iodine analysis
Potassium Iodide analysis
Radiation Dosage
Radio Waves
Vacuum
Chemical Fractionation methods
Iodine chemistry
Iodine radiation effects
Potassium Iodide chemistry
Potassium Iodide radiation effects
Sonication
Subjects
Details
- Language :
- English
- ISSN :
- 1350-4177
- Volume :
- 13
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Ultrasonics sonochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 16223678
- Full Text :
- https://doi.org/10.1016/j.ultsonch.2005.01.001