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Kinetic resolution of alpha-acetoxy N-acyl oxazolidinethiones by a chiral O-nucleophilic acyl transfer catalyst.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2005 Oct 05; Vol. 127 (39), pp. 13502-3. - Publication Year :
- 2005
-
Abstract
- The kinetic resolution of alpha-acetoxy N-acyl oxazolidinethiones using the chiral, nonracemic O-nucleophilic acyl transfer catalyst 8 is described. The reaction proceeds on a variety of substrates in excellent yields, with s-factors ranging from 17 to 31.
- Subjects :
- Catalysis
Kinetics
Stereoisomerism
Oxazoles chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 127
- Issue :
- 39
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 16190706
- Full Text :
- https://doi.org/10.1021/ja053743z