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Flow behavior of colloidal rodlike viruses in the nematic phase.

Authors :
Lettinga MP
Dogic Z
Wang H
Vermant J
Source :
Langmuir : the ACS journal of surfaces and colloids [Langmuir] 2005 Aug 16; Vol. 21 (17), pp. 8048-57.
Publication Year :
2005

Abstract

The behavior of a colloidal suspension of rodlike fd viruses in the nematic phase, subjected to steady state and transient shear flows, is studied. The monodisperse nature of these rods combined with relatively small textural contribution to the overall stress make this a suitable model system to investigate the effects of flow on the nonequilibrium phase diagram. Transient rheological experiments are used to determine the critical shear rates at which director tumbling, wagging, and flow-aligning occurs. The present model system enables us to study the effect of rod concentration on these transitions. The results are in quantitatively agreement with the Doi-Edwards-Hess model. Moreover, we observe that there is a strong connection between the dynamic transitions and structure formation, which is not incorporated in theory.

Details

Language :
English
ISSN :
0743-7463
Volume :
21
Issue :
17
Database :
MEDLINE
Journal :
Langmuir : the ACS journal of surfaces and colloids
Publication Type :
Academic Journal
Accession number :
16089419
Full Text :
https://doi.org/10.1021/la050116e