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Sterically-controlled regioselective para-substitutions of aniline.

Authors :
Dyer PW
Fawcett J
Griffith GA
Hanton MJ
Olivier C
Patterson AR
Suhard S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2005 Aug 14 (30), pp. 3835-7. Date of Electronic Publication: 2005 Jun 24.
Publication Year :
2005

Abstract

Introduction of sterically demanding 1-isopropyl-2-methylpropyl or triisopropylsilyl groups at the nitrogen of aniline allows high-yielding regioselective para-substitution to be achieved using a lithiation/substitution sequence.

Details

Language :
English
ISSN :
1359-7345
Issue :
30
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
16041433
Full Text :
https://doi.org/10.1039/b506824j