Back to Search Start Over

Synthesis and characterization of a Mo/Ag/Rb heterotrimetallic cluster with double-cage architecture.

Authors :
Lin P
Clegg W
Harrington RW
Henderson RA
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2005 Jul 21 (14), pp. 2349-51. Date of Electronic Publication: 2005 Jun 09.
Publication Year :
2005

Abstract

The first Mo/Ag/Rb heterotrimetallic cluster has been synthesised by a self-assembly reaction involving [Mo2O2S2edt2]2-, Ag+, Rb+, S2- and dibenzo-18-crown-6 (DB18C6); the structure consists of two [{Mo6Ag6O6S7edt6}2{Rb(DB18C6)}]3- units linked by Rb-C contacts.

Details

Language :
English
ISSN :
1477-9226
Issue :
14
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
15995741
Full Text :
https://doi.org/10.1039/b503447g