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Remarkable selectivity in addition of alcohols to epoxydienes of 5,7 bicyclic and 5,7,6 tricyclic systems.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2005 Feb 04; Vol. 70 (3), pp. 1077-80. - Publication Year :
- 2005
-
Abstract
- Acid-catalyzed addition of alcohols to tricyclic dienyl epoxides such as 4 or bicyclic vinyl oxiranes such as 17 exclusively occurred at the vinyl terminus of unsaturated system through a typical S(N)2' process affording 1,6- and 1,4-dioxygenated derivatives, respectively.
Details
- Language :
- English
- ISSN :
- 0022-3263
- Volume :
- 70
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 15675876
- Full Text :
- https://doi.org/10.1021/jo0481295