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Proton transfer and N(+)-H...S(-) hydrogen bonds in the crystal structure of 4-aminothiophenol.

Authors :
Jetti RK
Boese R
Thakur TS
Vangala VR
Desiraju GR
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Nov 21 (22), pp. 2526-7. Date of Electronic Publication: 2004 Oct 01.
Publication Year :
2004

Abstract

4-Aminothiophenol exists as 4-ammonio-1-benzenethiolate in the solid and liquid state. The crystal structure is characterised by a tetrahedral beta-As type network which is the driving force for the proton transfer.

Details

Language :
English
ISSN :
1359-7345
Issue :
22
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
15543262
Full Text :
https://doi.org/10.1039/b407319c