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New high-nuclearity Ni-Pt carbonyl clusters: synthesis and X-ray structure of the ordered [HNi24Pt17(CO)46]5- and the substitutionally Ni/Pt disordered [Ni32Pt24(CO)56]6- cluster anions.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Oct 21 (20), pp. 2274-5. Date of Electronic Publication: 2004 Sep 07. - Publication Year :
- 2004
-
Abstract
- Condensation between preformed Ni-Pt and Pt carbonyl clusters leads to the new [H(6-n)Ni(24)Pt(17)(CO)(46)](n-)(n= 5, 6) and the substitutionally Ni/Pt disordered [Ni(24)(Ni(12-x)Pt(x))Pt(20)(CO)(56)](6-) (x = 4) carbonyl clusters, the latter of which represents the highest nuclearity homoleptic carbonyl cluster anion so far reported.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 15489977
- Full Text :
- https://doi.org/10.1039/b409522g