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Remarkable room-temperature insertion of carbon monoxide into an aluminum-carbon bond of tri-tert-butylaluminum.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2004 Sep 29; Vol. 126 (38), pp. 11812-3. - Publication Year :
- 2004
-
Abstract
- Room-temperature reaction of carbon monoxide with tri-tert-butylaluminum at atmospheric pressure yields the dimeric tert-butylacyl complex [tBu2AlC(O)tBu]2 (1). This unprecedented CO insertion into an aluminum-carbon bond is apparently made possible by the three-coordinate aluminum center in the tri-tert-butylaluminum starting material.
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 126
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 15382914
- Full Text :
- https://doi.org/10.1021/ja046411n