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Asymmetric synthesis of secondary alcohols from primary alcohols via intramolecular carbenoid C-H insertion catalyzed by rhodium(II) 3-phenylcholestane-2-carboxylate.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Apr 07 (7), pp. 816-7. Date of Electronic Publication: 2004 Feb 23. - Publication Year :
- 2004
-
Abstract
- Chiral secondary alcohols may be prepared from primary alcohols via asymmetric C-H insertion reactions of alpha'-alkoxy-alpha-diazoketones catalyzed by rhodium(II)(2R,3R)-3-phenylcholestane-2-carboxylate.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 7
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 15045078
- Full Text :
- https://doi.org/10.1039/b316984g