Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity.

Authors :: Mareque-Rivas JC
Prabaharan R
de Rosales RT
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Jan 07 (1), pp. 76-7. Date of Electronic Publication: 2003 Nov 04.
Publication Year :: 2004
Abstract: The presence of second-sphere -NH(2) groups in the proximity of a zinc(ii)-bound water molecule enhances its acidity by ca. 2 pK(a) units.

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