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Ultrafast chemistry: cobalt carbonyl-mediated synthesis of diaryl ketones under microwave irradiation.

Authors :
Enquist PA
Nilsson P
Larhed M
Source :
Organic letters [Org Lett] 2003 Dec 11; Vol. 5 (25), pp. 4875-8.
Publication Year :
2003

Abstract

By combining the advantages of metal activation, in situ carbon monoxide delivery, and microwave heating, benzophenones were efficiently synthesized in 6-10 s. These ultrafast carbonylation reactions occur under air by flash heating of aryl iodides in the presence of dicobalt octacarbonyl. [reaction: see text]

Details

Language :
English
ISSN :
1523-7060
Volume :
5
Issue :
25
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
14653696
Full Text :
https://doi.org/10.1021/ol036091x