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Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalysts.

Authors :
Fiddy SG
Evans J
Newton MA
Neisius T
Tooze RP
Oldman R
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2003 Nov 07 (21), pp. 2682-3.
Publication Year :
2003

Abstract

Highly dilute EXAFS characterisation for the elucidation of species involved in Heck chemistry is demonstrated; the major "monomer" species of Herrmann's acetate-bridged phosphapalladadacycle is characterised and species present during the course of a 50 ppm [Pd] Pd(OAc)2/PBu(t)3 catalysed Heck reaction are presented.

Details

Language :
English
ISSN :
1359-7345
Issue :
21
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
14649809
Full Text :
https://doi.org/10.1039/b307535d