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Synthesis of ferrocene/hydrofullerene hybrid and functionalized bucky ferrocenes.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2003 Nov 19; Vol. 125 (46), pp. 13974-5. - Publication Year :
- 2003
-
Abstract
- Hydroferration reaction of [60]fullerene or its derivative with [Fe(C5H5)(CO)2]2 gives regioselectively a ferrocene/hydrofullerene hybrid, which upon treatment with Bu4NOH and an alkyl halide affords the corresponding alkylated bucky ferrocene, again regioselectivity via an anion of the ferrocene.
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 125
- Issue :
- 46
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 14611230
- Full Text :
- https://doi.org/10.1021/ja037335b