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Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO.

Authors :
Bellabarba RM
Tooze RP
Slawin AM
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2003 Aug 07 (15), pp. 1916-7.
Publication Year :
2003

Abstract

The novel complex (tbpx)PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.

Details

Language :
English
ISSN :
1359-7345
Issue :
15
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
12932031
Full Text :
https://doi.org/10.1039/b305854a