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Synthesis and antiviral evaluation of alpha-D-2',3'-didehydro-2',3'-dideoxy-3'-C-hydroxymethyl nucleosides.

Authors :
Yamada K
Hayakawa H
Sakata S
Yoshimura Y
Source :
Nucleic acids research. Supplement (2001) [Nucleic Acids Res Suppl] 2001 (1), pp. 79-80.
Publication Year :
2001

Abstract

A series of hydroxymethyl branched analogues of antiviral apio d4Ns was synthesized from D-arabinose. The SN2' ring opening reaction of 2,2'-anhydro-alpha-D-pyrimidinenucleoside (10) was mainly investigated. The reaction selectively gave SN2' adducts, which were deprotected to furnish the desired alpha-D-2',3'-didehydro-2',3'-dideoxy-3'-C-hydroxymethyl nucleosides (2).

Details

Language :
English
Issue :
1
Database :
MEDLINE
Journal :
Nucleic acids research. Supplement (2001)
Publication Type :
Academic Journal
Accession number :
12836273
Full Text :
https://doi.org/10.1093/nass/1.1.79