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Bis[mu-6-amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dionato-kappa3O4,N5:O5]-di-micro-aqua-bis[diaqua[6-amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dionato-kappa2N1,O2]strontium(II)]: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework.

Authors :
Low JN
Arranz P
Cuesta R
GutiƩrrez MD
Glidewell C
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2003 Jan; Vol. 59 (Pt 1), pp. m21-4. Date of Electronic Publication: 2002 Dec 10.
Publication Year :
2003

Abstract

The title complex, [Sr(2)(C(5)H(5)N(4)O(3))(4)(H(2)O)(6)], forms centrosymmetric dimers in which one water ligand bridges two Sr centres and in which one of the anionic ligands is bidentate and bonded to just one Sr atom, and the other is tridentate and bridges the two Sr centres within the dimer. The dimeric units are linked by an extensive series of O-H...O, O-H...N and N-H...O hydrogen bonds to form a complex three-dimensional framework.

Details

Language :
English
ISSN :
0108-2701
Volume :
59
Issue :
Pt 1
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
12506218
Full Text :
https://doi.org/10.1107/s0108270102021492