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C-Cl/Si-H exchange catalysed by P,N-chelated Pt(II) complexes.

Authors :
Stöhr F
Sturmayr D
Schubert U
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Oct 07 (19), pp. 2222-3.
Publication Year :
2002

Abstract

Alkyl chlorides R-Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(kappa 2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R-H and ClSiMe2Ph.

Details

Language :
English
ISSN :
1359-7345
Issue :
19
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
12397988
Full Text :
https://doi.org/10.1039/b205405a