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Intramolecular dealkylation of chelating diamines with Ru(II) complexes.

Authors :
Morilla ME
Morfes G
Nicasio MC
Belderrain TR
Mar Díaz-Requejo M
Graiff C
Tiripicchio A
Sánchez-Delgado R
Pérez PJ
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Sep 07 (17), pp. 1848-9.
Publication Year :
2002

Abstract

N,N, N',N'-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 degrees C to afford chelating amine ligands which contains one or two N-H functionalities.

Details

Language :
English
ISSN :
1359-7345
Issue :
17
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
12271639
Full Text :
https://doi.org/10.1039/b205078a