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Cerium masquerading as a group 4 element: synthesis, structure and computational characterisation of [CeCl(N(SiMe3)2)3].
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2001 Sep 07 (17), pp. 1560-1. - Publication Year :
- 2001
-
Abstract
- Oxidation of the three-coordinate cerium amide [Ce(N-(SiMe3)2)3] with TeCl4 in toluene solution yields purple, diamagnetic [CeCl(N(SiMe3)2)3], whose structure has been examined by X-ray crystallographic and computational methods.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 12240381
- Full Text :
- https://doi.org/10.1039/b103634n