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The first observation of the [Cp3Mn]- anion; structures of hexagonal [(eta 2-Cp)3MnK.1.5thf] and ion-separated [(eta 2-Cp)3Mn]2[Mg(thf)6].2thf.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2001 Oct 07 (19), pp. 1956-7. - Publication Year :
- 2001
-
Abstract
- Hexagonal [(eta 2-Cp)3MnK.1.5thf] 1 and ion-separated [(eta 2-Cp)3Mn]2[Mg(thf)6].2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn]- anion.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 12240237
- Full Text :
- https://doi.org/10.1039/b106366a