Back to Search
Start Over
Novel reactivity of SeO2 with 1,3-dienes: selenophene formation.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2002 Sep 06; Vol. 67 (18), pp. 6553-6. - Publication Year :
- 2002
-
Abstract
- A novel and efficient method for the synthesis of selenophenes is disclosed. Selenophenes were synthesized in high yields in a single operation from 1,3-dienes containing a carbonyl group at the C-1 position and selenium dioxide. The bidirectional synthesis of selenophenes can also be demonstrated using this method. The selenophene is believed to form via a [4 + 2] cycloaddition between diene and selenium dioxide.
Details
- Language :
- English
- ISSN :
- 0022-3263
- Volume :
- 67
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 12201782
- Full Text :
- https://doi.org/10.1021/jo025630t