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Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Mar 07 (5), pp. 482-3. - Publication Year :
- 2002
-
Abstract
- Stable, uncoordinated (1-[2-(6-trimethylsilyl)pyridyl]-3-[(2,6- diisopropyl)phenyl]imidazol-2-ylidene), I, and (1-[beta-(diphenylphosphino)ethyl]-3-[(2,6-diisopropyl)phenyl]imidazol- 2-ylidene), II, have been synthesised; in the solid state they adopt a conformation with the lone pairs in a mutually anti arrangement.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 12132484
- Full Text :
- https://doi.org/10.1039/b111659b