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Asymmetric deactivation of racemic BINAP-Ru(II) catalysts through complete enantiomer discrimination by dimethylbinaphthylamine: highly enantioselective hydrogenation of olefin and beta-keto ester.
- Source :
-
Organic letters [Org Lett] 2002 May 16; Vol. 4 (10), pp. 1643-5. - Publication Year :
- 2002
-
Abstract
- [reaction: see text] 3,3'-Dimethyl-2,2'-diamino-1,1'-binaphthyl (DM-DABN) is designed as a "chiral poison" (deactivator) for complete enantiomer resolution of racemic BINAP-Ru(II) catalysts in a highly enantioselective hydrogenation of beta-keto ester and kinetic resolution of racemic 2-cyclohexen-1-ol.
Details
- Language :
- English
- ISSN :
- 1523-7060
- Volume :
- 4
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 12000263
- Full Text :
- https://doi.org/10.1021/ol0256567