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On the short carbonyl bond in bis[mu-1,2-benzisothiazol-3(2H)-one 1,1-dioxido-kappa2N:O]bis[[1,2-benzisothiazol-3(2H)-one 1,1-dioxido-kappaN]bis(imidazole)copper(II)].

Authors :
Naumov P
Jovanovski G
Hu SZ
Suh IH
Razak IA
Chantrapromma S
Fun HK
Ng SW
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2001 Sep; Vol. 57 (Pt 9), pp. 1016-9. Date of Electronic Publication: 2001 Sep 11.
Publication Year :
2001

Abstract

The short carbonyl bond in the title compound, [Cu(2)(C(7)H(4)NO(3)S)(4)(C(3)H(4)N(2))(4)] [Liu, Huang, Li & Lin (1991). Acta Cryst. C47, 41-43], is an artifact of disorder in the isothiazol-3(2H)-one 1,1-dioxide part of the 1,2-benzisothiazol-3(2H)-one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five-coordinate Cu atom shows trigonal-bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two-dimensional layer structure.

Details

Language :
English
ISSN :
0108-2701
Volume :
57
Issue :
Pt 9
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
11588355
Full Text :
https://doi.org/10.1107/s0108270101009507