Supramolecular aggregates of complex cations via unusual purine-purine base pairing in a new organorhodium(III) compound containing the antileukemic drug purine-6-thione. Synthesis, X-ray structure of trans(C,N7),trans(S,S),trans(P,N7)-[Rh(C6H5)(H1,H9- H2tp)2(PPh3)][Rh(C6H5)(H1,H9-H2tp)(H9-Htp)(PPh3)]Cl3.HCl.6H2O, and density functional analysis of the [H2tp...Htp]- base pair.

Authors :: Cini R
Corsini M
Cavaglioni A
Source :: Inorganic chemistry [Inorg Chem] 2000 Dec 11; Vol. 39 (25), pp. 5874-8.
Publication Year :: 2000

Subjects :: Antimetabolites, Antineoplastic chemistry
Crystallography, X-Ray
Models, Molecular
Molecular Conformation
Organometallic Compounds chemical synthesis
Purines
Mercaptopurine chemistry
Organometallic Compounds chemistry
Rhodium

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