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Total synthesis of Amaryllidaceae alkaloids utilizing sequential intramolecular heterocyclic azadiene Diels-Alder reactions of an unsymmetrical 1,2,4,5-tetrazine.

Authors :
Boger DL
Wolkenberg SE
Source :
The Journal of organic chemistry [J Org Chem] 2000 Dec 29; Vol. 65 (26), pp. 9120-4.
Publication Year :
2000

Abstract

Convergent total syntheses of anhydrolycorinone, hippadine, and anhydrolycorinium chloride are detailed, enlisting sequential inverse electron demand Diels-Alder reactions of an unsymmetrical N-acyl-6-amino-1,2,4,5-tetrazine.

Details

Language :
English
ISSN :
0022-3263
Volume :
65
Issue :
26
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
11149859
Full Text :
https://doi.org/10.1021/jo0012546