A Catalytic Enantioselective Electron Transfer Reaction: Titanocene-Catalyzed Enantioselective Formation of Radicals from meso-Epoxides.

Authors :: Gansäuer A
Lauterbach T
Bluhm H
Noltemeyer M
Source :: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 1999 Oct 04; Vol. 38 (19), pp. 2909-2910.
Publication Year :: 1999
Abstract: A rationally designed titanium(III) catalyst allows the opening of epoxides with high enantioselectivity. This reaction [Eq. (1)] constitutes the first example of an enantioselective transition metal catalyzed radical reaction that proceeds by electron transfer.

Language :: English
ISSN :: 1521-3773
Volume :: 38
Issue :: 19
Database :: MEDLINE
Journal :: Angewandte Chemie (International ed. in English)
Publication Type :: Academic Journal
Accession number :: 10540389
Full Text :: https://doi.org/10.1002/(sici)1521-3773(19991004)38:19<2909::aid-anie2909>3.0.co;2-y

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