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Effect of reducing system on capacitive behavior of reduced graphene oxide film: Application for supercapacitor.

Authors :
Akbi, Hamdane
Yu, Lei
Wang, Bin
Liu, Qi
Wang, Jun
Liu, Jingyuan
Song, Dalei
Sun, Yanbo
Liu, Lianhe
Source :
Journal of Solid State Chemistry. Jan2015, Vol. 221, p338-344. 7p.
Publication Year :
2015

Abstract

To determine the best chemical reduction of graphene oxide film with hydriodic acid that gives maximum energy and power density, we studied the effect of two reducing systems, hydriodic acid/water and hydriodic acid/acetic acid, on the morphology and electrochemical features of reduced graphene oxide film. Using acetic acid as solvent results in high electrical conductivity (5195 S m −1 ), excellent specific capacitance (384 F g −1 ) and good cyclic stability (about 98% of its initial response after 4000 cycles). Using water as a solvent, results in an ideal capacitive behavior and excellent cyclic stability (about 6% increase of its initial response after 2100 cycles). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00224596
Volume :
221
Database :
Academic Search Index
Journal :
Journal of Solid State Chemistry
Publication Type :
Academic Journal
Accession number :
99900148
Full Text :
https://doi.org/10.1016/j.jssc.2014.10.004