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Catalytic effects of Na2CO3 additive on coal pyrolysis and gasification.
- Source :
-
Fuel . Feb2015, Vol. 142, p134-144. 11p. - Publication Year :
- 2015
-
Abstract
- Catalytic pyrolysis and gasification characteristics of coal using Na 2 CO 3 as a catalyst were studied in a high-frequency furnace and thermogravimetric analyzers (TGA), respectively. Interactions of Na 2 CO 3 with carbon at both pyrolysis and gasification phases were observed by in-situ heating stage microscope. The effects of pyrolysis temperature (650–800 °C) and catalyst loading amount (0–15 wt.%) on the associated pyrolysis and gasification processes were investigated. The results show that, H 2 and CO are the main pyrolysis gas products and the yields of these two gas increase with the increasing of Na 2 CO 3 in the range of 0–15 wt.%. The in-situ heating stage experiments indicated that one main gasification reaction form was observed for Shenfu char samples. Most of SF char particles reacted with CO 2 in the form of shrinking core mode without cracking, and certain particles presented fragmentation phenomenon in the reaction process. There is an optimal loading amount of Na 2 CO 3 for the best catalytic gasification effect of Shenfu bituminous char, while Na 2 CO 3 does not reach the saturation amount for the catalytic gasification of Zunyi anthracite coal. The activation energy of catalytic Shenfu coal gasification with 10 wt.% Na 2 CO 3 is 31.5 kJ mol − 1 less than that of non-catalytic coal gasification, which indicates that Na 2 CO 3 can improve the kinetics of coal gasification with CO 2 . [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00162361
- Volume :
- 142
- Database :
- Academic Search Index
- Journal :
- Fuel
- Publication Type :
- Academic Journal
- Accession number :
- 99793746
- Full Text :
- https://doi.org/10.1016/j.fuel.2014.11.010