Atomic transitions of Rb, D2 line in strong magnetic fields: Hyperfine Paschen–Back regime.

An efficient λ /2-method ( λ is the resonant wavelength of laser radiation) based on nanometric-thickness cell filled with rubidium is implemented to study the splitting of hyperfine transitions of 85 Rb and 87 Rb D 2 lines in an external magnetic field in the range of B =3–7 kG. It is experimentally demonstrated that at B > 3 kG from 38 (22) Zeeman transitions allowed at low B -field in 85 Rb ( 87 Rb) spectra in the case of σ + polarized laser radiation there remain only 12 (8) which is caused by decoupling of the total electronic momentum J and the nuclear spin momentum I (hyperfine Paschen–Back regime). Note that at B > 4.5 kG these 20 atomic transitions are regrouped into two completely separate groups of 10 atomic transitions each. Their frequency positions and fixed (within each group) frequency slopes, as well as the probability characteristics, are determined. A unique behavior of two atomic transitions is stressed: one transition belongs to 85 Rb, the other to 87 Rb and for low magnetic fields they could be presented as transitions F g = 3 , m F =+ 3 → F e = 4 , m F =+ 4 and F g = 2 , m F =+ 2 → F e = 3 , m F =+ 3 , correspondingly. The experimental results of the atomic transition frequency shifts and the modification of their probabilities agree well with the theory. A comparison of the behavior of the D 1 and D 2 atomic transitions is presented. Possible applications are described. [ABSTRACT FROM AUTHOR]