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High performance Li1·2(Mn0·54Co0·13Ni0·13)O2 with AlF3/carbon hybrid shell for lithium ion batteries.
- Source :
-
Materials Technology . Nov2014, Vol. 29 Issue A2, pA70-A76. 7p. - Publication Year :
- 2014
-
Abstract
- A kind of core shell cathode material, (LMSAC) was prepared by coating AlF3 and carbon hybrid layer on the surface of lithium rich manganese based solid solution (LMSS) through a sol-gel process. It was characterised by X-ray diffraction (XRD) patterns, scanning electron microscope (SEM) and transmission electron microscope (TEM). Its electrochemical properties were evaluated by electrochemical impedance spectra and galvanostatic charge-discharge measurements. Owing to the AlF3/C shell, the LMSAC could deliver the initial capacities of 278, 260, 246, 230 and 210 mAh g−1 at the rates of 0·1, 0·2, 0·5, 1 and 2C in the potential range of 2-4·8 V (versus Li+/Li) respectively, exhibiting an excellent rate capability. The corresponding coulombic efficiencies are 90, 89, 87, 88 and 85% in the first cycle. After cycled at the 0·1C and 1C rates for 50 times, the LMSAC remains 97 and 96% of the initial capacities respectively, displaying an enhanced cycling performance. The results suggest that surface coating of AlF3/C hybrid layer could be a promising method to improve the electrochemical properties of the LMSS cathode materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10667857
- Volume :
- 29
- Issue :
- A2
- Database :
- Academic Search Index
- Journal :
- Materials Technology
- Publication Type :
- Academic Journal
- Accession number :
- 99386693
- Full Text :
- https://doi.org/10.1179/1753555714Y.0000000180