Silver-promoted trans-hydrofluorination of ynamides: a regio- and stereoselective approach to (Z)-α-fluoroenamides.

Authors :: Che, Jianwei
Li, Yinglong
Zhang, Fang
Zheng, Renwei
Bai, Yihui
Zhu, Gangguo
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Nov2014, Vol. 55 Issue 45, p6240-6242. 3p.
Publication Year :: 2014
Abstract: A highly regio- and stereoselective trans -hydrofluorination of N -sulfonyl ynamides has been realized with AgF as the fluorination reagent, affording ( Z )-α-fluoroenamides in good to excellent yields. The reaction proceeds under mild reaction conditions and shows good functional group compatibility. [ABSTRACT FROM AUTHOR]

Subjects :: *SILVER nanoparticles
*FLUORINATION
*YNAMIDES
*STEREOSELECTIVE reactions
*SULFONYL compounds

Language :: English
ISSN :: 00404039
Volume :: 55
Issue :: 45
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 99060874
Full Text :: https://doi.org/10.1016/j.tetlet.2014.09.072

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