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Synthesis of Tenuifolin through Intramolecular Nicholas Reaction.
- Source :
-
Synlett . 2014, Vol. 25 Issue 17, p2467-2470. 4p. - Publication Year :
- 2014
-
Abstract
- The synthesis of the Cinnamomum homosesquiterpenoid tenuifolin has been accomplished by way of an intramolecular Nicholas reaction of the [Co2(CO)6] complex of an alkyne-substituted biaryl for construction of the seven-membered ring. The cyclization features the reaction of a nonactivated arene ring with the propargyldicobalt cation to give the dibenzocycloheptyne-Co2(CO)6. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 25
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 98763517
- Full Text :
- https://doi.org/10.1055/s-0034-1379009