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Stereoselective Cyclopropanation in the Synthesisof 3′-Deoxy-3′-C-hydroxymethyl-2′,3′-methylene-uridine.
- Source :
-
Organic Letters . Sep2014, Vol. 16 Issue 18, p4878-4880. 3p. - Publication Year :
- 2014
-
Abstract
- The synthesis ofthe novel 2′,3′-cyclopropane nucleoside3′-deoxy-3′-C-hydroxymethyl-2′,3′-methylene-uridineis described. Stereoselective construction of the cyclopropane ringwas achieved via Simmons–Smith cyclopropanation of a benzylprotected silyl enol ether, which was itself derived from 1,2-O-isopropylidene-α-d-xylofuranose. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 16
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 98501889
- Full Text :
- https://doi.org/10.1021/ol502383c