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Reduction of (Re(X)(CO)3(R'-DAB)] (X=Otf-, Br-; DAB=diazabutadiene; R'=iPr, pTol, pAn) and [Re...

Authors :
Rossenaar, Brenda D.
Hartl, Frantisek
Source :
Inorganic Chemistry. 10/09/96, Vol. 35 Issue 21, p6194. 10p. 5 Diagrams, 3 Charts, 4 Graphs.
Publication Year :
1996

Abstract

Describes the reduction routes of inorganic complexes and metal-alkyl complexes, using data obtained from IR and UV-vis spectroelectrochemical measurements and cyclic voltammetry at variable temperatures. Materials and preparations; IR spectral changes in the carbonyl stretching region during the reduction; Establishment of a one-electron reduction.

Subjects

Subjects :
*INORGANIC compounds

Details

Language :
English
ISSN :
00201669
Volume :
35
Issue :
21
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
9704184382
Full Text :
https://doi.org/10.1021/ic9600947