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Synthesis of Spiro Diphosphines and Their Application in Asymmetric Hydrogenation of Ketones.

Authors :
Jian-Hua Xie
Li-Xin Wang
Yu Fu
Shuo-Fei Zhu
Bao-Min Fan
Hai-Feng Duan
Qi-Lin Zhou
Source :
Journal of the American Chemical Society. 4/16/2003, Vol. 125 Issue 15, p4404. 2p. 2 Diagrams, 1 Chart.
Publication Year :
2003

Abstract

Details the synthesis of spiro diphosphines. Application in asymmetric hydrogenation of ketones; Steps in the catalytic asymmetric hydrogenation of prochiral ketones; Activity and enantioselectivity.

Subjects

Subjects :
*PHOSPHINE
*KETONES
*HYDROGENATION

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
15
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9591997
Full Text :
https://doi.org/10.1021/ja029907i